Hi, Susan,
When you create a new item, you need to allow it at a location(s).
Then, if you've entered the picking sequence number into the item record directly on the Units tab, you'll need to receive a quantity of the item before you'll be able to see the Pick Seq # in inquiries on the Quantities tab.
Otherwise, if you want to see the picking sequence number immediately in inquiries on the Quantities tab, use the Edit | Item Mtce | Picking Sequence function to enter the Pick Seq # on the item.
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Regards,
Softrak Tech Support