Hi Ryan,
If you want the 'Tax to Vendor' and other tax fields populated with the tax amount, the Tax Group must be defined for jurisdictions with a 'Costing method' of either 'Payables' or 'Both A/P and I/C'. If the costing method of a tax jurisdiction is instead set to either 'G/L only' or 'Inventory', then purchase orders will not display tax for the vendor.
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Regards,
Softrak Tech Support