There is no such option for AR statements as they are not forms in the same manner as invoices and orders. The print status of an invoice or picking slip determines processing status in many companies. AR statements can be reprinted at will and have no accounting ramifications. If desired, you can record the generation of a statement for a customer in their notes by enabling this option in the Company profile.

No one has requested this modification in Receivables, so there are no current plans to do this development.
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Andrew Bates